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3-(diallylamino)propanenitrile ((C3H5)2NC2H4CN, L) π-complexes with copper(I) ionic salts. Syntheses and crystal structures of compounds [Cu(H+L)ClO4]ClO4· H2O, [Cu(H+L)BF4]BF4· H2O, and [Cu(H+L)(H2O)]SiF6· H2O

✍ Scribed by M. Yu. Luk’yanov, A. V. Pavlyuk, E. A. Goreshnik, M. G. Mys’kiv


Book ID
115518726
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
517 KB
Volume
38
Category
Article
ISSN
1070-3284

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Single crystals of Lu(ClO 4 ) 3 ´3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ´6 H 2 O at 140 °C under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)°, b = 79.18(2), c = 63.83(2), R all = 0.