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3-Desamino-3α-hydroxysolanocapsine—a steroidal alkaloid from Solanum aculeatum

✍ Scribed by F. Coll; A. Preiss; M. Basterechea; J.L. Mola; G. Adam

Book ID
103338943
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
170 KB
Volume
22
Category
Article
ISSN
0031-9422

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✍ Quyen, Le Thi ;Ripperger, Helmut ;Schreiber, Klaus 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 674 KB

## Abstract The steroid alkaloid soladunalinidine [5α‐tomatidan‐3β‐amine, (25__S__)‐5α,22β__N__‐spirosolan‐3β‐amine, 2], isolated from __Solanum dunalianum__, is synthesized from tomatidine (5α‐tomatidan‐3β‐ol, 1) via 5α‐tomatidan‐3‐one (4) and its oxime 5 which is reduced to 2 as well as to its ri