In the title compound, C~27~H~25~NO, all three rings in the azabicyclo[2.2.2]octane unit adopt a boat conformation. An intermolecular C—H...O interaction forms a characteristic __R__ ~2~ ^2^(14) motif dimer in the crystal packing.
3-Benzylidene-1-(2,6-dichlorophenyl)indolin-2-one
✍ Scribed by Thamotharan, S. ;Parthasarathi, V. ;Vijayalakshmi, L. ;Anuradha, B. ;Desai, Bhavik ;Shah, Anamik
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 156 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The phenyl and dichlorophenyl rings of the title molecule, C 21 H 13 Cl 2 NO, are oriented at angles of 39.3 (1) and 77.8 (1) , respectively, with respect to the central indoline ring. The crystal structure is stabilized by van der Waals interactions.
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The molecular structure of (I), showing the atom-numbering scheme. Displacement ellipsoids are drawn at the 40% probability level.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.057 wR factor = 0.141 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
View of the molecule of (I), showing the atom-labeling scheme. Displacement ellipsoids are drawn at the 30% probability level.