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3-(Acylamino)-3-amino-2-nitroacrylonitriles from N-Acyl-S-methyl-3,3-diamino-2-nitroacrylthioimidates

✍ Scribed by María I. García Trimiño; Anthony Linden; Heinz Heimgartner; Arturo Macías Cabrera

Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
781 KB
Volume
76
Category
Article
ISSN
0018-019X

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✦ Synopsis

Reaction of N-acyI-3,3-diamino-2-nitroacrylthioamides 1 with Me1 at room temperature leads to N-acyl-Smethyl-3,3-diamino-2-nitroacrylthioimidates 2 in moderate yields. The latter react with Hg(OAc), in DMF yielding 3-(acylamino)-3-amino-2-nitroacrylonitriles 8. The structures of' Za and 8a were established by X-ray crystallography. ') A similar behavior of thioimidate esters toward Hg salts has been reported by Hall and Satchel1 [16]. *) Atomic coordinates, bond lengths, and bond angles have been deposited with the Cambridge Crystallographic Data Ceiztre, 12 Union Road, Cambridge CB2 IEZ, England.

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