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[3 + 3] Cyclodimerization of Methylenecyclopropanes: Stoichiometric and Catalytic Reactions of Nickel(0) with Electron-Deficient Alkylidenecyclopropanes

✍ Scribed by Ohashi, Masato; Taniguchi, Tomoaki; Ogoshi, Sensuke

Book ID
126798598
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
907 KB
Volume
29
Category
Article
ISSN
0276-7333

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3 Ο© 2] Co-cyclization / Nickel(0) catalysis / Palladium(0) catalysis / 4-Methylenespiro [2.4] ## heptane derivatives Bicyclopropylidene (1) readily undergoes a palladium(0)-ca-ates 2aΟͺ5 with the electron deficient alkenes and the cycloadducts 6 and 7 with the strained alkenes in acceptable to tal