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3-(2,2′:6′,2′′-Terpyridin-4′-yloxy)propyl toluene-4-sulfonate

✍ Scribed by Hoogenboom, Richard ;Nakahashi, Akiko ;Kickelbick, Guido ;Chujo, Yoshiki ;Schubert, Ulrich S.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
216 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 25 H 23 N 3 O 4 S, was synthesized by tosylation of 3-(2,2 0 ;6 0 ,2 00 -terpyridin-4 0 -yloxy)propan-1-ol. The dihedral angles formed by the substituent pyridine rings with the central ring are 4.27 (4) and 17.27 (5) . The crystal packing is stabilized by intermolecular C-HÁ Á ÁO hydrogen-bond interactions, with no stacking interaction between the aromatic rings.


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The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha