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2α-Hydroxy-3α-[N-alkyl(aryl)]pinanoamines. Part I. Preparation and nature of some Schiff bases of 2α-hydroxypinan-3-one. Crystal and molecular structure of α-hydroxy-2,6,6-trimethylbicyclo[3.1.1]hepta-3-ylidenaminobenzene

✍ Scribed by Stanislaw Wojciech Markowicz; Janina Karolak-Wojciechowska; Witold Kwiatkowski


Publisher
Springer
Year
1989
Tongue
English
Weight
454 KB
Volume
19
Category
Article
ISSN
1572-8854

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Preparation and crystal and molecular st
✍ Peter Köll; Wolfgang Saak; Siegfried Pohl; Bohumil Steiner; Miroslav Koóš 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 858 KB

The title compound was isolated by several recrystallisations from a 1:l mixture of diastereomers which was obtained in 75% yield from the reaction of 1,2:3,4-di-O-isopropylidene-c~-D-galactopyranose with epichlorohydrin. The absolute configuration of this isomer (30% yield) was established by X-ray