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(2S,5S)-2,5-dibenzyl-1,4-dimethylpiperazine, a novel alkaloid from zanthoxylum arborescens

✍ Scribed by Jonas A. Grina; Frank R. Stermitz

Book ID: 104243591
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 133 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92474-8

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✦ Synopsis

The isolation and structure determination of (2S,5S)-2,5-dibenzyl-1,4-dimethylpiperam, a new alkaloid biogenetically related to L-phenylalanine diketopiperazine, is described Dreyer investigated1 the alkaloid content of seed husks from Zanthoxylum arborescens Rose, a Mexican member of the citrus family (Rutaceae), and found two new quinazolones. We have been investigating the leaves, bark, and wood of this species and have found a number of alkaloids. The structure of one of these is described here. Dried, ground leaves were extracted with hexane and then with MeOH. The residue from the MeOH extraction was dissolved in dil. aq. H2S04. This solution was extracted with CHCl,, made

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