(2R,4S,7R,9S)-5,6-Diisopropyl-1,10-dimethoxy-3,8-dimethyldeca-3,4,6,7-tetraene-2,9-diol
✍ Scribed by Poonoth, Manojkumar ;Schürmann, Markus ;Preut, Hans ;Krause, Norbert
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 363 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The molecule of the title compound, C~20~H~34~O~4~, is centrosymmetric. In the crystal structure, a network of O—H...O hydrogen bonds result in each molecule being linked to four neighbouring molecules and a two-dimensional net is formed.
📜 SIMILAR VOLUMES
The title compound, C 12 H 22 N 2 O 6 , is a linearly fused di(trihydroxypiperido)piperazine. The three six-membered rings adopt chair conformations with all the hydroxyl groups equatorial, and the ring fusion is the unusual trans±cisoid±cis.
Single-crystal X-ray study T = 291 K Mean (C-C) = 0.006 A R factor = 0.053 wR factor = 0.136 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
**(+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐2,7‐dioxa‐twista‐4,9‐diene.** A synthesis and the determination of the sense of chirality of (+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐2,7‐dioxa‐twista‐4,9‐diene ((+)‐**5** and (−)‐