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[2]Pseudorotaxane Formation with N -Benzylanilinium Axles and 24-Crown-8 Ether Wheels

โœ Scribed by Loeb, Stephen J.; Tiburcio, Jorge; Vella, Sarah J.

Book ID
127228857
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
136 KB
Volume
7
Category
Article
ISSN
1523-7060

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A New Motif for the Self-Assembly of [2]
A New Motif for the Self-Assembly of [2]Pseudorotaxanes; 1,2-Bis(pyridinium)ethane Axles and [24]Crown-8 Ether Wheels
โœ Stephen J. Loeb; James A. Wisner ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 125 KB

Multiple intramolecular interactions help to stabilize the novel [2]pseudorotaxanes formed from 1,2-bis(pyridinium)ethane dications (which act as axles) and 24-membered crown ethers (which act as wheels; see structure). This is the first successful sythesis of [2]pseudorotaxanes with [24]crown-8 as