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296. Periodate oxidation of deoxy-hexoses and their derivatives

โœ Scribed by Lee, J. B.

Book ID
121224230
Publisher
The Royal Society of Chemistry
Year
1960
Weight
502 KB
Category
Article
ISSN
0368-1769

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The electron-releasing homoconjugated ca
The electron-releasing homoconjugated carbonyl group. Application to the total syntheses of 3-deoxy-, 4-deoxy-hexose, lividosamine and derivatives
โœ Daniela Fattori; Etienne de Guchteneere; Pierre Vogel ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 298 KB

The regioselective electrophilic addition of benzeneselenyl bromide to (-)-(lS,4S)-7~oxabicyclo/2.2.lihept-S-en-2-one were exploited to develop efficient syntheses of methyl 3-deoxy-a-D-arabino-hexofuranoside and 4-deoxy-D-lyxo-hexopyraose. Similarly, D-lividosamine (3-deoxy-D-glucosamine) was deriv