29 Si Chemical Shift Anisotropies in Calcium Silicates from High-Field 29 Si MAS NMR Spectroscopy
✍ Scribed by Hansen, Michael Ryan; Jakobsen, Hans J.; Skibsted, Jørgen
- Book ID
- 120983561
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 232 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
29Si chemical shifts in a wide variety of silicates in crystalline, glassy and gel states have been related to a parameter, P, which takes into account the electronegativity and the structural description of the silicate units as well as the ionic potential of the modifier cation. The relation, G(pp
The nine resonances in the hitherto unassigned %i magic-angle-spinning NMR spectrum of tricalcium silicate (C$) are tentatively assigned using a 6 versus dsro correlation between isotropic %i chemical shifts ( ) and mean Si-0 bond lengths (ds,,) observed for the a;-, B\_, and y-dicalcium silicate (C