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29 Si Chemical Shift Anisotropies in Calcium Silicates from High-Field 29 Si MAS NMR Spectroscopy

✍ Scribed by Hansen, Michael Ryan; Jakobsen, Hans J.; Skibsted, Jørgen


Book ID
120983561
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
232 KB
Volume
42
Category
Article
ISSN
0020-1669

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29Si chemical shifts in a wide variety of silicates in crystalline, glassy and gel states have been related to a parameter, P, which takes into account the electronegativity and the structural description of the silicate units as well as the ionic potential of the modifier cation. The relation, G(pp

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✍ Jørgen Skibsted; Jens Hjorth; Hans J. Jakobsen 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 391 KB

The nine resonances in the hitherto unassigned %i magic-angle-spinning NMR spectrum of tricalcium silicate (C$) are tentatively assigned using a 6 versus dsro correlation between isotropic %i chemical shifts ( ) and mean Si-0 bond lengths (ds,,) observed for the a;-, B\_, and y-dicalcium silicate (C