27Al and29Si NMR study of sol-gel derived aluminosilicates and sodium aluminosilicates
β Scribed by A. D. Irwin; J. S. Holmgren; J. Jonas
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 414 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-2461
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π SIMILAR VOLUMES
The empirical correlation of 2gSi NMR chemical shifts 6 and the mean SIOT (T = Al. 5%) bond angles a in sibcates and alutiosili~tes is explained by a simple quantum-chemical model. A linear mrrelatlon 6 = 6 o + M + b cos a/(cos a -1) is derived, where n is the number of Al atoms in the Si(OSi)q \_n(
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