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263. A new synthesis of para-substituted benzils, and preparation of some of the corresponding benzoins

โœ Scribed by van Es, T. ;Backeberg, O. G.

Book ID
120335960
Publisher
The Royal Society of Chemistry
Year
1963
Weight
639 KB
Category
Article
ISSN
0368-1769

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The catalync p-benzoqumone or au oxldaaon of benzoin to bennl was camed out m the presence of Pen&-o-xyl)#-(o-xyl = o-xylene-a. a'-&thlolate) or [Fen(S+Bu)&-m a ratlo [benzomlficatalyst] = 20/l m DMF at 25 'C Under such mild reacnon condmons, the Fe(II) thiolate complex exhibited high catalync activ