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[2,6-iPr2C6H3(Me3Si)NTl]4—A Covalent Thallium(I)-Nitrogen Compound with Weak Arene–Thallium Interactions

✍ Scribed by Dipl.-Chem. Said D. Waezsada; Dipl.-Chem. Thomas Belgardt; Dr. Mathias Noltemeyer; Prof. Dr. Herbert W. Roesky


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
221 KB
Volume
33
Category
Article
ISSN
0044-8249

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[2,6-iPr2C6H3(Me3Si)NTI]4 eine kovalente
✍ Said D. Waezsada; Thomas Belgardt; Dr. Mathias Noltemeyer; Prof. Dr. Herbert W. 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 242 KB

Durch schwache Aren‐Thallium‐Wechselwirkungen und TlTl‐Kontakte stabilisiert sich das Molekülgerüst der tetrameren Titelverbindung im Festkörper. Das Bild rechts zeigt zwei Monomereinheiten sowie den zentralen Ti~4~‐Ring. Diese erste kovalente Tl^1^‐Verbindung kann leicht aus LiN(SiMe~3~)(2,6__i__

Synthesis and Crystal Structure of [(1-(
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The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ