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2,6-Dimethoxy-4-(5-oxo-2-phenyl-4,5-dihydro-1,3-oxazol-4-ylidenemethyl)phenyl acetate

✍ Scribed by Sun, Yi-Feng ;Wang, Xin-Li ;Li, Ji-Kun ;Zheng, Ze-Bao ;Wu, Ren-Tao


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
422 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C~20~H~17~NO~6~, was synthesized by the reaction of syringaldehyde with hippuric acid. The molecule adopts a Z configuration about the central olefinic bond. The two benzene rings and the oxazolone ring are almost coplanar. The crystal structure is stabilized by weak intermolecular C—H...O hydrogen bonds.


📜 SIMILAR VOLUMES


2-Methoxy-4-[2-methyl-5-oxo-4,5-di­hydro
✍ Wang, Xiangqian ;Zhang, Mingjie ;Qi, Zhaobin ;Ma, Shanshan 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 89 KB

In the title compound, C 14 H 13 NO 5 , the C atom between the benzene and oxazolone rings displays a distorted trigonal bonding geometry. The oxazolone and aromatic rings are approximately coplanar.

Methyl (4-oxo-1-phenyl-4,5-dihydro-1H-py
✍ Yathirajan, H. S. ;Bindya, S. ;Sarojini, B. K. ;Narayana, B. ;Bolte, Michael 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 501 KB

The title compound, C 14 H 12 N 4 O 3 , a pyrazolopyrimidine derivative, displays normal geometrical parameters. The dihedral angle between the mean planes of the pyrazolopyrimidine unit and the phenyl ring is 26.14 (4) . The non-H atoms of the ester side chain are coplanar (r.m.s. deviation = 0.009

Ethyl (4-oxo-1-phenyl-1,4-dihydro-5H-pyr
✍ Yathirajan, H. S. ;Bindya, S. ;Sarojini, B. K. ;Narayana, B. ;Bolte, Michael 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 372 KB

Geometric parameters of the title compound, C 14 H 12 N 4 O 3 , a pyrazolopyrimidine derivative, are in the usual ranges. The dihedral angle between the pyrazolopyrimidine system and the phenyl ring is 4.64 (5) . The non-H atoms of the ester side chain lie in a common plane (r.m.s. deviation = 0.028

1-(3,5-Di­methoxy­phenyl)-2-{2-[(3,5-dim
✍ Yin, Qiang ;Zhang, Wen-Qin 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 416 KB

The title compound, C 26 H 30 O 7 , was obtained by the Grignard reaction of one molecule of 4-methoxybenzylmagnesium chloride with two molecules of 3,5-dimethoxybenzaldehyde. The two new chiral centers have the same absolute con®guration R (S), and the two hydroxyl groups, surrounded by the three b