2,6-Diiodophenyl acridine-9-carboxylate
✍ Scribed by Sikorski, Artur ;Krzymiński, Karol ;Białońska, Agata ;Lis, Tadeusz ;Błażejowski, Jerzy
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 477 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the orthorhombic crystalline phase of the title compound, C 20 H 11 I 2 NO 2 , all the benzene rings are parallel, whereas the acridine systems are either parallel or perpendicular to each other; this generates a herring-bone pattern. The acridine systems and benzene rings are inclined at an angle of 45.5 (1) to each other, and the acridine systems and carboxylate groups are inclined at an angle of 54.2 (1) . Oppositely oriented consecutive molecules, withinteractions between their acridine systems and IÁ Á ÁI and IÁ Á ÁN contacts, are aligned in stacks along the a axis. These stacks, interacting throughcontacts between benzene rings, are arranged in layers.
📜 SIMILAR VOLUMES
In the title compound, C 21 H 17 NO 4 S, all bond lengths and angles show normal values. The sulfonyl-bound phenyl ring forms a dihedral angle of 88.31 (1) with the mean plane of the carbazole fragment. The crystal packing is stabilized by weak intermolecular -, C-HÁ Á Á and C-HÁ Á ÁO interactions.
The title compound, C 13 H 10 ClN 5 O 2 , crystallizes with two molecules in the asymmetric unit. These are connected by ®ve hydrogen bonds, viz. three NÐHÁ Á ÁN interactions, two longer C OÁ Á ÁÁHÐN interactions, bifurcated at the O atom, and a CÐHÁ Á ÁN contact.