2,6-Bis[2,4-bis(heptyloxy)phenyl]pyridine
✍ Scribed by Alcock, Nathaniel W. ;Rourke, Jonathan P
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 279 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title 2,6-disubstituted pyridine, C 41 H 61 NO 4 , with a crystallographic twofold axis, has an arrangement of molecules well organized to undergo multiple cyclometallation reactions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.038 wR factor = 0.102 Data-to-parameter ratio = 10.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.002 A Ê R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the molecule of the title compound, C~25~H~27~N~3~, the two 2,6-dimethyl-substituted phenyl rings are connected to the pyridine ring __via__ the C=N imine bonds. Although the compound includes three N atoms, there are no obvious hydrogen-bond or π–π interactions in the crystal structure.