✦ LIBER ✦
25Mg-NMR: A Method for the Characterization of Organomagnesium Compounds, their Complexes, and Schlenk Equilibria
✍ Scribed by Dr. Reinhard Benn; Prof. Dr. Herbert Lehmkuhl; Klaus Mehler; Dr. Anna Rufińska
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 236 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
Predominantly covalent Mg—C bonds are present in dicyclopentadienylmagnesium, as indicated by ^25^Mg‐NMR spectroscopy. The large range of the ^25^Mg chemical shifts (ca. 200 ppm) also facilitates clarification of other controversial bonding behavior. For the investigation of Schlenk equilibria [eq. (a)], the method has the advantage that all three species can be identified directly.
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