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2,5-Di-O-acetyl-3-C-methyl-d-lyxono-1,4-lactone

✍ Scribed by Bream, Richard ;Watkin, David ;Soengas, Raquel ;Eastwick-Field, Vanessa ;Fleet, George W. J.


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
418 KB
Volume
62
Category
Article
ISSN
1600-5368

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Single-crystal X-ray study T = 190 K Mean '(C±C) = 0.002 A Ê R factor = 0.031 wR factor = 0.078 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The relative configuration at C-2 of the title lactone, C 14 H 22 O 6 , which exists in the five-membered ring form, was unequivocally established by X-ray crystallographic analysis. The absolute configuration was determined by the use of 2,4-di-Cmethyl-l-arabinose as the starting material.

3,5-Di-C-methyl-5,6-O-isopropylidene-l-g
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The relative configuration at position C-2 of the title lactone, C 11 H 18 O 6 , which exists in the five-membered ring form, was unequivocally established by X-ray crystallographic analysis. There are two molecules present in the asymmetric unit (Z 0 = 2). The absolute configuration was determined

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The relative configuration at position C-2 of the title lactone, C 11 H 18 O 6 , which exists in the five-membered ring form, was unequivocally established by X-ray crystallographic analysis. The absolute configuration was determined by the use of 2,4di-C-methyl-l-arabinose as the starting material.