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2,5-Bis[(Z)-2-nitrobenzenesulfenylmethylene]-3,6-bis(methylene)-7-oxabicyclo[2.2.1]heptane. A versatile reagent for tandem regioselective Diels-Alder reactions

✍ Scribed by Tornare, Jean Marc; Vogel, Pierre


Book ID
126249928
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
284 KB
Volume
49
Category
Article
ISSN
0022-3263

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Diels-alder stereo- and regioselectivity
✍ Jean-Luc MΓ©tral; Pierre Vogel πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 131 KB

T7ze regioseZectivity of the EtAlCZ -cataZyzed addition of methyl vinyl ketone to the titZe diene can be reversed by solvent modz &cation. 9 The chemical properties of the diene moieties in 2,3-bis(methylene)bicycloC2.2.l]alkanes can be affected by remote substitution at C(5) and C(6).' For example