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2,4,6-Trialkylphenyl-2H-phospholes from Slightly Aromatic 1H-Phospholes and Their Use in [4 + 2] Cycloaddition Reactions.

✍ Scribed by Gyoergy Keglevich; Renata Farkas; Timea Imre; Krisztina Ludanyi; Aron Szoelloesy; Laszlo Toeke


Book ID
101942855
Publisher
John Wiley and Sons
Year
2003
Weight
101 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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2,4,6-Trialkylphenyl-2H-phospholes from
✍ György Keglevich; Renáta Farkas; Tímea Imre; Krisztina Ludányi; Áron Szöllősy; L 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 80 KB

## Abstract 1‐(2,4,6‐Trialkylphenyl)phospholes **__1a,b__** possess a moderate aromatic character. Despite of that they underwent a sigmatropic rearrangement at 150°C to afford 2H‐phospholes **__2a,b__** which by trapping with tolane, or in reaction with another unit of **__2__** gave [4 + 2] cyclo