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(2,4,6-Tri-tert-butylphenylimino)thioxo-and -selenoxophosphoranes. Synthesis and structural characterization

✍ Scribed by Vadim D. Romanenko; Alexander V. Ruban; Andrei B. Drapailo; Alexander N. Chernega; Eduard B. Rusanov

Book ID
118283723
Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
564 KB
Volume
3
Category
Article
ISSN
1042-7163

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Crystal structure of 2,4,6-tri-tert-buty
Crystal structure of 2,4,6-tri-tert-butylphenyltrichlorogermane and 2,4,6-tri-tert-butylphenylgermane
✍ Masafumi Unno; Yuuki Kawai; Hideyuki Matsumoto πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 140 KB

## Abstract Two organogermanium compounds, 2,4,6‐(t‐Bu)~3~C~6~H~2~GeCl~3~ (1) and 2,4,6‐(t‐Bu)~3~C~6~H~2~GeH~3~ (2), were prepared, and the structures were determined by X‐ray crystallography. Compound 1 exhibits unusual structural parameters due to the strong repulsion of the bulky t‐butyl substit