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2,4-Diene-1,6-diones and 2-Acyl-3-cyclopenten-1-ols by Double Friedel-Crafts Acylation of Tricarbonyl(diene)iron Complexes

✍ Scribed by Directeur de Recherche au CNRS Michel Franck-Neumann; Dr. Madjid Sedrati; Dr. Mohamed Mokhi

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 235 KB
Volume: 25
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198611311

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✦ Synopsis

A further aspect emerges from a comparison of the Si-Si bonds in 1, 2, and 4 : if one assumes that the bonds of the Si, ring in 1 are arched, then the "analog calculation" with a model kit'" using the Si-Si distance of 251 pm gives a value of 265 pm for the linear bond. This would then be the "normal" length of an Si-Si bond between two atoms with /err-butyl groups as substituents.

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