𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2,4-Di­chloro­phenyl 4-toluene­sulfonate: supramolecular aggregation through C—H⋯O, C—H⋯Cl, C—H⋯π and π⋯π interactions

✍ Scribed by Vembu, Nagarajan ;Nallu, Maruthai ;Garrison, Jered ;Youngs, Wiley J.

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
978 KB
Volume
59
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the crystal structure of the title molecule, C 13 H 10 Cl 2 O 3 S, the dihedral angle between the mean planes of the 4-tolyl and 2,4dichlorophenyl rings is 43.92 (4) . There are weak CÐHÁ Á ÁO hydrogen bonds, which generate rings of motifs S(5), S(6), R 2 1 (4), R 1 2 (6) and R 2 2 (8). The supramolecular aggregation is completed by the presence of CÐHÁ Á ÁCl, CÐHÁ Á Á% and %Á Á Á% interactions.

📜 SIMILAR VOLUMES

Phenyl 4-toluene­sulfonate: supramolecul
Phenyl 4-toluene­sulfonate: supramolecular aggregation through weak C—H⋯O and C—H⋯π interactions
✍ Manivannan, Vadivelu ;Vembu, Nagarajan ;Nallu, Maruthai ;Sivakumar, Kandasamy ;L 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

In the crystal structure of the title compound, C 13 H 12 O 3 S, the dihedral angle between the mean planes of the 4-tolyl and phenyl rings is 52.6 (1) . There are weak C-HÁ Á ÁO hydrogen bonds, which generate rings of graph-set motifs R 1 2 (4) and R 2 1 (9). The supramolecular aggregation is compl

4-Methoxy­phenyl 4-toluene­sulfonate: su
4-Methoxy­phenyl 4-toluene­sulfonate: supramolecular aggregation through C—H⋯O and C—H⋯π interactions
✍ Vembu, Nagarajan ;Nallu, Maruthai ;Garrison, Jered ;Hindi, Khadijah ;Youngs, Wil 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 617 KB

Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê R factor = 0.058 wR factor = 0.128 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.