2,3,7,8-Tetra-2-pyridylpyrazino[2,3-g]quinoxaline dihydrate
✍ Scribed by Neels, Antonia ;Stoeckli-Evans, Helen
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 283 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 30 H 18 N 8 Á2H 2 O, is a solvate of 2,3,7,8tetra(pyridin-2-yl)pyrazino[2,3-g]quinoxaline and, like the latter, is crystallographically centrosymmetric. The pyrazine ring makes dihedral angles of 54.95 (6) and 28.09 (6) with the two independent pyridine rings. The two pyridine rings are inclined to one another by 56.77 ( 7) , with their N atoms facing each other. In the crystal structure, adjacent molecules are linked by O-HÁ Á ÁN hydrogen bonds, forming a wide ribbon-like structure extending in the ac plane.
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The title compound, C~20~H~12~Cl~2~N~2~, was synthesized from the reaction of equimolar amounts of 4,5-dichlorobenzene-1,2-diamine and benzil in acetonitrile, utilizing molecular iodine as the catalyst. The crystal structure was determined at 110 K. The dihedral angle between the two phenyl rings is
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