✦ LIBER ✦

2,3,4,5,6-Pentafluoroaniline

✍ Scribed by Gdaniec, Maria

Book ID: 104490961
Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 469 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807023197

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✦ Synopsis

In the title compound, C 6 H 2 F 5 N, the N atom of the amino group deviates by 0.19 (2) A ˚from the plane of its bonded atoms and thus has slightly pyramidal sp 2 hybridization. The crystal packing is governed largely by N-HÁ Á ÁF interactions and interaction of F atoms with the perfluorophenyl ring (C-FÁ Á Á F = 3.21 and 3.25 A ˚). Intermolecular N-HÁ Á ÁF hydrogen bonds link molecules into polar sheets parallel to the (100) plane.

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