2,3,4-Trichloro-6-(diethylamino)-9-oxo-9H-xanthene-1-carboxylic acid methanol solvate
✍ Scribed by Zhang, Hai-Feng ;Sun, Bao-Sheng ;Zhao, Xin-Hua ;Yan, Fan-Yong
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 179 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title compound, C 26 H 27 NO 4 , the central ring of the xanthene moiety is planar and the two outer rings are in halfboat conformations. The molecular packing in the crystal structure is stabilized by N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds in addition to van der Waals forces.
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.007 A Ê R factor = 0.075 wR factor = 0.196 Data-to-parameter ratio = 10.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
A concise cnantioselective synthesis of (3S,6S,9S)-2-oxo-3-(N-Boc-amino)-lazabicyclo[4.3.0]nonane-9-carboxylic acid methyl ester from N-protected glutamic acid is described. O 1997 Elsevier Science Ltd.