2,3,3′,4′-Tetramethylbiphenyl
✍ Scribed by Robertson, Andrew J. ;Price, Daniel J.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 257 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
2,3,3 0 ,4 0 -Tetramethylbiphenyl, C 16 H 18 , was synthesized in a palladium-catalysed boronic acid cross-coupling reaction. In the solid state, these weakly interacting unsymmetrical molecules show an apparent dimerization of the orthodimethylphenyl groups, a packing motif that is seen in a significant number of other ortho-dimethylphenyl-containing compounds.
📜 SIMILAR VOLUMES
In the title molecule, C 22 H 19 NO 2 S, the thiazolidinone ring exhibits a flattened envelope conformation. The methoxyphenyl and biphenyl substituents are in pseudo-equatorial and pseudo-axial orientations, respectively, with respect to the thiazolidinone ring.
The title compound, C~26~H~26~N~2~O~7~, is a thiamidine derivative. Geometric parameters are in the usual ranges. The crystal packing is stabilized by a classical N—H...O hydrogen bond, several weak C—H...O hydrogen bonds and a π–π stacking interaction.
The title compound, C 33 H 25 BrN 4 , belongs to the class of substituted tetrazoles. This type of compound is an important starting material for the synthesis of pharmaceutically active materials.