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[2,3]-Wittig rearrangement on carbohydrate template. Novel approach to chiral synthesis of 3-alkylmalic acids

✍ Scribed by Katsumi Kakinuma; Hui-Yin Li

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 239 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99347-x

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✦ Synopsis

Dianion [2,3]

-Wittig rearrangement of tertiary a-(allyloxy)-acetic acid systems on a carbohydrate template has achieved efficient chirality transfer to furnish diastereoselective chiral synthesis of 3-alkylmalic acid.

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