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[2,3]-Wittig rearrangement of nonracemic (propargyloxy)acetic acids and esters. Synthesis of optically active 2,5-dihydrofurans

โœ Scribed by Marshall, James A.; Wang, Xiao Jun


Book ID
118744344
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
872 KB
Volume
55
Category
Article
ISSN
0022-3263

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Stereoselective [2, -Wittig rearrangement of E-and Z-allylic stannyl ethers derived from an isopropylidene L-threitol derivative has been investigated. The E-isomer exhibited best diastereoselectivity and the resulting rearrangement product has been converted to protected polyoxamic acid, an amino