3-Deoxy-DL-prumycin (1) was synthesized from 2-furanmethanol (2-furfuryl alcohol, 2) in eleven steps in 15% total yield. Michael addition of azide anion to 2,3-dideoxy-oqent-2-enopyranos~ulose (3) and reduction in situ of the adduct afforded the key intermediates 5 and 6. Introduction of a second ax
2,3-Dideoxy-DL-pentose
β Scribed by Price, Charles C.; Balsley, Richard B.
- Book ID
- 126310838
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 327 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
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