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2,3-Bis(2-pyridyl)-5,8-quinoxalinediones with metal chelating properties: Synthesis and biological evaluation

✍ Scribed by Sylviane Giorgi-Renault; Patricia Gebel-Servolles; Philippe Helissey; Jean Renault; Jean-Luc Bernier; Jean-Pierre Henichart; Suzanne Cros


Book ID
102916140
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
810 KB
Volume
78
Category
Article
ISSN
0022-3549

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5,15-bis(8-quinolyl)- and -bis(2-pyridyl
✍ Yasuhiro Aoyama; Takao Kamohara; Atsushi Yamagishi; Hiroo Toi; Hisanobu Ogoshi πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 266 KB

5,15-Bis(8-quinolyl)octaethylporphyrin gives stable and isolable atropisomers, but the 5,15-bis(2-pyridyl) analog does not. The quinolyl group has no interaction with the central metal, but it readily binds external metal. Also described is the novel dimerization of Rh(II1) complex induced by intra