Single-crystal X-ray study T = 178 K Mean '(C±C) = 0.006 A Ê R factor = 0.068 wR factor = 0.219 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
[2.2]Basketenoparacyclophane 18,20-dicarbonitrile
✍ Scribed by Jones, Peter G. ;Witulski, Bernhard ;Hopf, Henning
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 200 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.040 wR factor = 0.117 Data-to-parameter ratio = 12.7
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title compound, C 20 H 12 N 2 , the fused ring system leads to angle strain (e.g. sp 3 angles of ca 98 or ca 130 ). The molecules are linked by one CÐHÁ Á ÁN and two CÐHÁ Á Á% interactions to form layers perpendicular to [101].
The structure of the title compound, [Zn(C 92 H 60 N 4 )-(C 2 H 3 N)]ÁC 2 H 3 N, shows relatively small saddle-type distortion with ruf¯ing, compared to other dodecaphenylporphyrin complexes.