𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2,2′,3,3′,6,6′-Hexachloro-5-nitro-1,1′-biphenyl (5-Nitro PCB 136)

✍ Scribed by Shaikh, Nadim S. ;Parkin, Sean ;Lehmler, Hans-Joachim

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
126 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 12 H 3 Cl 6 NO 2 , has a dihedral angle of 83.92 (8) between the benzene rings. It was obtained as an intermediate in the synthesis of 3-hydroxy PCB 136 by nitration of PCB 136.

📜 SIMILAR VOLUMES

6,6′-Dimethoxy-2,3,2′,5′-tetranitro-1,1′
6,6′-Dimethoxy-2,3,2′,5′-tetranitro-1,1′-biphenyl
✍ Xiao, Xue-Yang ;Miao, Shao-Bin ;Lan, Hong-Hong ;Jiang, Yuan-Yuan ;Ji, Bao-Ming 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 1010 KB

The title compound, C 14 H 10 N 4 O 10 , was obtained by nitration of 6,6 0 -dimethoxy-2,2 0 -dinitro-1,1 0 -biphenyl in the presence of an excess of fuming nitric acid. In the molecule, the dihedral angle between the two benzene rings is 89.9 (2) . In the crystal structure, molecules are connected

3,5-Di­nitro­xytri­cyclo­[2.2.1.02,6]­he
3,5-Di­nitro­xytri­cyclo­[2.2.1.02,6]­heptane
✍ Öztürk, Sema ;Büyükkıdan, Bülent ;Akkurt, Mehmet ;Çakmak, Osman ;Fun, Hoong-Kun 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 252 KB

The molecule of the title compound, C 7 H 7 N 2 O 6 , has a mirror plane through three common C atoms of two ®ve-membered rings, which show distorted envelope conformations. The nitroxy group is in a planar con®guration.

2,3,5,6-Tetra­methyl­pyrazine–p-nitro­ph
2,3,5,6-Tetra­methyl­pyrazine–p-nitro­phenol (1/2)
✍ Cai, Xiao-Qing ;Hu, Mao-Lin ;Zhao, Ya-Juan ;Cheng, Ya-Qian ;Wang, Shun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 288 KB

methylpyrazine and two p-nitrophenol molecules form a centrosymmetric unit. Intermolecular O-HÁ Á ÁN and weak C-HÁ Á ÁO hydrogen bonds are observed in the structure, leading to the formation of a two-dimensional network.

2-(2-Nitro­phenyl)-4,5-benz-1,3-oxazin-6
2-(2-Nitro­phenyl)-4,5-benz-1,3-oxazin-6-one
✍ Yadav, Bishwa Nath ;Prasad, Shambhu ;Prasad, Satya Murti 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 210 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.038 wR factor = 0.105 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.