Cyclophanes, XXXV. DNMR, molecular mecha
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Bodwell, Graham J. ;Ernst, Ludger ;Hopf, Henning ;Jones, Peter G. ;McNally, John
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Article
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1990
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Wiley (John Wiley & Sons)
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English
⚖ 515 KB
## Abstract The syntheses of 2,11‐dithia[3,3]orthometacyclophane (5) and 2,11‐dithia[3,3]orthoparacyclophane (6) by dithiol‐dibromide coupling are described. Whereas the yield of 5 is not significantly affected by the substrate pairing, that of 6 is. Both compounds exhibit a temperature‐dependent ^