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[2.2.1]Propellane

โœ Scribed by Walker, Frederick H.; Wiberg, Kenneth B.; Michl, Josef


Book ID
127091726
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
290 KB
Volume
104
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


[2.2.2]Propellane system
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A Remarkable [2.2.2]Propellane
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[3.3.1]-propellane-2,8-dione
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The title compound was prepared by transammlar addition of a carbene to an exocyclic double bond. Rhodium acetate catalyzed decomposition of 2-diazo-&methylene-1,3-cyclooctanedione gave 1 quantitatively. We wish to report the first synthesis of the title compound, 1, and a new approach to propellan