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2,2″-Dimethoxy-1,1′:3′,1″-terphenyl as a novel protective group for low-coordinated phosphorus compounds: The case of diphosphenes

✍ Scribed by Alex S. Ionkin; William J. Marshall

Book ID: 102231772
Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 128 KB
Volume: 14
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.10162

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✦ Synopsis

Abstract

A synthetic approach to meta‐terphenyls iodides bearing methoxy groups in the 2 and 2′′′ positions has been described. 2,2″‐Dimethoxy‐1,1′:3′,1″‐terphenyl groups have been shown to stabilize diphosphenes in solution. The existence of conformers of the diphosphene 7 has also been recorded. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:360–360, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10162

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