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2,2'-Dicarbomethoxy-9,9'-bitriptycyl. Synthesis, conformational stability, and separation and identification of the conformers

โœ Scribed by Schwartz, Leonard H.; Koukotas, Constantine; Kukkola, Paivi; Yu, Chen Shek


Book ID
127122106
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
679 KB
Volume
51
Category
Article
ISSN
0022-3263

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The 1,9, 17 -triaza[2 2.21 metacyclophane-2, 10, 18-trlone derlvatlves (1) -( 2) have been synthesised X-Ray crystallography shows that the 1,9, 17trimethyl derivative (3) adopts a Crown conformation (11) m the solid state. n m r. spectroscopy lndlcates that both the 1, 9-dlmethyl-17-benzyl- (2) a