(2,2′-Bipyridine)dichlorogold(III) nitrate
✍ Scribed by Bjernemose, Jens K. ;Raithby, Paul R. ;Toftlund, Hans
- Book ID
- 104482800
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 294 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [AuCl 2 (C 10 H 8 N 2 )]NO 3 , is layered parallel to (101) by %±% stacking. The individual {101} layers are held together by extensive CÐHÁ Á ÁO and CÐHÁ Á ÁCl hydrogen bonding.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.009 A Ê R factor = 0.053 wR factor = 0.126 Data-to-parameter ratio = 18.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.014 A Ê R factor = 0.071 wR factor = 0.156 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [CuCl 2 (C 10 H 8 N 2 )], has twofold symmetry and the coordination geometry around the Cu II atom is distorted square-planar. There are weak intermolecular CuÁ Á ÁCl interactions, forming a chain structure in the crystal.