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207Pb NMR study of novel Pb–Pb chemical bonding in lead monoxides, α-PbO and β-PbO

✍ Scribed by S.P. Gabuda; S.G. Kozlova; V.V. Terskikh; C. Dybowski; G. Neue; D.L. Perry


Book ID
108312887
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
146 KB
Volume
305
Category
Article
ISSN
0009-2614

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NMR-spectroscopic study of 207Pb in pure
✍ Michael Fechtelkord; Ulrich Bismayer 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 413 KB

31P and 207Pb MAS and static 207Pb NMR spectra of Pb3(PO4)2 and (Pb1-xBa(x))3(PO4)2 (x = 0.08, 0.12) are analysed. The resonances stemming from different cation sites are correlated with the corresponding local symmetry and their oxygen neighbours. The coordination sphere of Pb(1) consists of 12 oxy