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2-Thienylpalladium(II) formation as a common step of oxidative coupling and hydroxylation of thiophene in aqueous solutions of palladium salts

โœ Scribed by Rudakov, E. S. ;Ignatenko, V. M.


Book ID
112683816
Publisher
Springer
Year
1983
Tongue
English
Weight
181 KB
Volume
22
Category
Article
ISSN
0133-1736

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โœ John W. Francis; Patrick M. Henry ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 899 KB

In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for