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2-tert-Butoxy-1-phenyl-1-(2,2,6,6-tetra­methyl­piperidin-1-yl­oxy)­ethane

✍ Scribed by Batsanov, Andrei S. ;Reid, Alistair J. ;Cameron, Neil


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
132 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 21 H 35 NO 2 , contains a piperidine ring in a chair conformation, with a pyramidal N atom and a single (exocyclic) N-O bond in an equatorial orientation.


📜 SIMILAR VOLUMES


(2E)-2-(1-Methyl­piperidin-2-yl­idene)-1
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Single-crystal X-ray study T = 173 K Mean (C-C) = 0.003 A Disorder in main residue R factor = 0.051 wR factor = 0.199 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title compound, C~27~H~50~N~2~O~4~, was prepared from butylmalonic acid and 1,2,2,6,6-pentamethyl-4-hydroxypiperidine by transesterification. In the molecule, both piperidine rings adopt chair conformations.