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2-Silyloxy-1,2-oxazines, a New Type of Acetals of Conjugated Nitroso Alkenes

✍ Scribed by Tishkov, Alexander A.; Lesiv, Alexey V.; Khomutova, Yulya A.; Strelenko, Yury A.; Nesterov, Ivan D.; Antipin, Michael Yu.; Ioffe, Sema L.; Denmark, Scott E.


Book ID
121401164
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
121 KB
Volume
68
Category
Article
ISSN
0022-3263

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Synthesis of 6H-1,2-oxazines by hetero D
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6H-1,2-Oxazines / Methoxyallene / Nitroso alkene / Hetero Diels-Alder reaction Regioselective hetero Diels-Alder reactions of in-situ generated nitroso alkenes 2-4 with methoxyallene derivatives 1 provide 4H-1,2-oxazines 5-7 with an exo-methylene group at C-5. These primary cycloadducts are smoothly