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2-Phospha-4-silabicyclo[1.1.0]butane as a Reactive Intermediate

✍ Scribed by J. Chris Slootweg; Frans J. J. de Kanter; Marius Schakel; Andreas W. Ehlers; Barbara Gehrhus; Martin Lutz; Allison M. Mills; Anthony L. Spek; Koop Lammertsma

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
199 KB
Volume
116
Category
Article
ISSN
0044-8249

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2-Phospha-4-silabicyclo[1.1.0]butane as
2-Phospha-4-silabicyclo[1.1.0]butane as a Reactive Intermediate
✍ J. Chris Slootweg; Frans J. J. de Kanter; Marius Schakel; Andreas W. Ehlers; Bar πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 200 KB

Bicyclo[1.1.0]butane remains a fascinating compound. Stretching of its central CΓ€C s-bond culminates in a planar singlet diradical transition structure for inversion, [1] whereas stretching of the peripheral bonds leads to valence isomerization. [2] Bridging heteroatoms affect both processes. They e