ule have proposed a general mechanism for the light-induced isomerization of heteroaromatic i-oxides using tile quinoline i-oxide system as a model (3).
2-Phenylquinoline 1-oxide
✍ Scribed by Fahlquist, Henrik ;Healy, Peter C. ;Young, David J. ;Tiekink, Edward R. T.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 254 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 15 H 11 NO, is not planar, as seen in the dihedral angle of 41.92 (12) formed between the quinoline and phenyl residues. This conformation allows the crystal structure to be stabilized by C-HÁ Á ÁO interactions. Zigzag chains along the a direction, mediated by C-HÁ Á ÁO interactions, may be discerned in the crystal structure and these stack along the c direction, again via C-HÁ Á ÁO interactions. Interactions of the type C-HÁ Á Á serve to stabilize the zigzag chains and to provide links between them.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.003 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.