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2-phenyl-1,3-benzodithiolylium trifluoromethanesulfonate: A reagent for the conversion of alcohols into benzyl ethers and benzoates under mild conditions.

โœ Scribed by Mauro Mocerino; Robert V. Stick

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
197 KB
Volume
31
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Absrrucr: 2-Phenyl-1,3benzodithiolylium trifluoromethanesulfonate, easily prepared from 1,2benzenedithiol, converts alcohols into dithioorthoesters and, ultimately, benzyl ethers (Bu@H) and benzoates (HgCYHBF4).

Recently, Ganem reported the conversion of alcohols into benzyl ethers utilizing phenyldiazomethane under mild acidic conditi0ns.t As well. Sekine introduced the 2-(methylthio)phenylthiomethyl group for the protection of alcohols, easily removable (HgClz)

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