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2-Methylbutanal as a probe molecule and the production of isoprene on stoichiometric and nonstoichiometric B-P-O catalysts

✍ Scribed by J.B. Moffat; A. Schmidtmeyer


Book ID
119509423
Publisher
Elsevier Science
Year
1986
Weight
434 KB
Volume
28
Category
Article
ISSN
0166-9834

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The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads