The title compound, C 14 H 12 N 2 O 4 , exists as an enol-imine tautomer, in which a strong intramolecular O-HÁ Á ÁN hydrogen bond is formed. This study verifies the preference of the enol-imine tautomeric form in the solid state.
✦ LIBER ✦
2-Methoxy-3-nitrophenol
✍ Scribed by Behrman, David M. ;Behrman, E. J. ;Parkin, Sean
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 354 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The crystal structure of 2-methoxy-3-nitrophenol, C~7~H~7~NO~4~, is stabilized by hydrogen bonds and π–π stacking interactions.
📜 SIMILAR VOLUMES
(E)-4-Methoxy-2-[(4-nitrophenyl)imino
✍
Ko˛sar, Bąsak ;Albayrak, Çiğdem ;Odabaşoğlu, Mustafa ;Büyükgüngör, Orhan
📂
Article
📅
2005
🏛
International Union of Crystallography
🌐
English
⚖ 187 KB
4-(2-Methoxy-4-nitrophenyldiazenyl)p
✍
You, Xiu-Li ;Zhang, Yan ;Zhang, De-Chun
📂
Article
📅
2006
🏛
International Union of Crystallography
🌐
English
⚖ 236 KB
4-Methoxy-2-nitroaniline
✍
Rosli, Mohd Mustaqim ;Patil, P. S. ;Fun, Hoong-Kun ;Razak, Ibrahim Abdul ;Dharma
📂
Article
📅
2007
🏛
International Union of Crystallography
🌐
English
⚖ 220 KB
2-Methoxy-4-(phenyliminomethyl)pheno
✍
Lin, Zhi-Dong ;Lin, Zhi-Dong ;Li, Xing ;Huang, Ya-min
📂
Article
📅
2005
🏛
International Union of Crystallography
🌐
English
⚖ 103 KB
3-(4-Hydroxy-3-methoxy-2-nitrophenyl
✍
Xia, Chun-Nian ;Hu, Wei-Xiao ;Zhou, Wei
📂
Article
📅
2006
🏛
International Union of Crystallography
🌐
English
⚖ 86 KB
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.006 A Disorder in main residue R factor = 0.095 wR factor = 0.243 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
2,3-Bis(bromomethyl)-1-methoxy-4-nitr
✍
Qin, Shuqi ;Yin, Guodong ;Zhou, Baohan
📂
Article
📅
2005
🏛
International Union of Crystallography
🌐
English
⚖ 170 KB