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(2-Hydroxyphenylmethylene)bis(phosphine oxides): a facile rearrangement into 2-(phosphinylmethyl)phenyl phosphinates

✍ Scribed by Bovin, Alexander N.; Yarkevich, Alla N.; Kharitonov, Alexander V.; Tsvetkov, Eugene N.

Book ID
119973620
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
235 KB
Volume
8
Category
Article
ISSN
0022-4936

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## Abstract Bis(2‐phenylphosphinoethyl)phenylphosphine, PhP(CH~2~CH~2~PPh~2~)~2~, reacts with lithium in tetrahydrofuran to give the corresponding lithium bis(2‐diphenylphosphidoethyl)phenylphosphine, Li~2~[PhP(CH~2~CH~2~PPh)~2~]. The lithium diphosphide is identified by NMR spectroscopy and furthe